Think it was Peter Shilton 1967 against Leicester.
http://news.bbc.co.uk/sport1/hi/football/16343401.stm
GOALSCORING GOALKEEPERS
Charlie Williams (Man City) v Sunderland, 1900
Pat Jennings (Tottenham) v Man Utd, 1967
Peter Shilton (Leicester) v Southampton, 1967
Peter Schmeichel (Man Utd) v Rotor Volgograd, 1995
Jimmy Glass (Carlisle) v Plymouth, 1999
Peter Schmeichel (Aston Villa) v Everton, 2001
Brad Friedel (Blackburn) v Charlton, 2004
Paul Robinson (Tottenham) v Watford, 2007
Kelvin Davis (Pompey) v Southampton 2012